Sure, Lively, 25, has had her fair share of men; she’s dated everyone from Leonardo DiCaprio to Ryan Gosling.
But it’s hard to go wrong with a guy like Reynolds, who is so good-looking, he snagged PEOPLE’s coveted Sexiest Man Alive title, in 2010.
In honor of the couple’s rumored nuptials, Celebuzz is taking a look back at Reynolds’ sexiest moments, both on the big screen and off. Check them out in our gallery, above.
Reynolds, 35, and Lively were married Sunday evening in Mt. Pleasant, SC, after a year of dating, according to multiple sources.
They met while working on the set of The Green Lantern, which hit theaters in 2011.