WATCH: Justin Timberlake and Chris Stapleton Duet at 2015 CMAs

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Justin Timberlake and country music darling, Chris Stapleton, teamed up for the most talked-about performance of this year’s Country Music Awards on Wednesday night.

The twosome teamed up for two songs together. The first was their version of the classic George Jones song “Tennessee Whiskey,” which Timberlake, Stapleton and his wife, Morgane, crooned soulfully with a brass band backing them.

The second song was “Drink You Away” from Timberlake’s album, The 20/20 Experience delivered with a decidedly country twang that revealed Justin’s homegrown Tennessee roots.

In addition to his show-stopping performance with JT, Stapleton was the big winner of the night at the CMAs when he nabbed the male vocalist of the year award as well as the title of album of the year for Traveller.