For the stars of Mad Men, getting nominated for an Emmy isn't the problem -- it's winning one. No actor from the acclaimed AMC drama has managed to walk away with TV's top prize. However, it was a memorable season for Moss and her character Peggy Olson, who took a competing offer and left the firm in the Season 5. That episode, titled “The Other Woman,” is the one the actress submitted for consideration. Unfortunately for Moss, it will take a huge upset for her to become the night's golden girl. Emmy chances: Minimal.