'Gossip Girl' Hookup List
Nate and Ivy/Charlie - Ivy Dickens (Kaylee DeFer) plays her role well. After all, pretending to be Charlie Rhodes and caring for Rhodes matriach, Cece, got her the money she wanted. Ivy and Nate first kiss as she competes to be one of Blair's bridesmaids. The aspiring actress develops feelings for the hunk but is threatened by Diana to stay away from him. Her true identity is revealed after she becomes the cause of a major car accident which injures Blair and Chuck.
Source: Giovanni Rufino/The CW