'Gossip Girl' Hookup List
Nate and Lola/Charlie - The real Charlie Rhodes (Ella Rae Peck) caught Nate's eye when she was going by the name of Lola as a waitress at Blair's epic and disastrous wedding. The two began dating as she investigated Ivy (Kaylee DeFer) who was pretending to be her. Jaws dropped when we found out she is actually Serena's sister as her dad slept with sisters, Lilly (Kelly Rutherford) and Carol (Sheila Kelly). Lola left Nate for her touring acting troupe at the end of the fifth season.
Source: Giovanni Rufino/The CW