3. Jessica Chastain
If there were a best-dressed hall of fame for red carpet newcomers, Chastain, who’s nominated for a Golden Globe for her role in Zero Dark Thirty, would surely top it. She landed on all the right lists after the Golden Globes and Oscars last year, plus she made it on Vanity Fair’s international best-dressed roundup (only Duchess Kate could top her). Even though we’re certain she’ll be perfectly coiffed (it’s so predictable!), we’re still anxious to see just how she’ll do it (her red carpet style is never predictable, which is half the fun of watching her) .