Gomez, who was on the show to promote her new film Rudderless, did not disappoint in her navy blue ensemble.
Looking drop dead gorgeous in Tom Ford and Chanel, the actress and singer finished off her look with a loose ponytail and bangs.
Chanel x Tom Ford #oliviapopestyle
Olivia Pope would be so proud.
Launch the gallery, above, for more photos of Selena Gomez heading into the El Capitan Theatre in Hollywood.
Rudderless opens Friday.